Launching on June 8 next summer, the flights will operate on Tuesday, Thursday and Saturday on a Boeing 767-300 ER aircraft featuring premium and economy cabins.
Prices lead in at £687.02 for a return economy seat on the flight which is on sale now and which has been launched in conjunction with a separate Frankfurt-Vancouver service, also in June.
Benjamin Smith, Air Canada president, passenger airlines, said: “Air Canada continues to strategically increase its European flights at YVR with seasonal daily flights to Frankfurt next summer and three times weekly flights to London Gatwick.