Some 35 airlines, including the likes of Virgin Atlantic, Delta Airlines, Emirates and Air France, are set to be affected by a strike by refuelling operatives at Heathrow airport, starting Saturday 4 May.
The union said the 72-hour walkout risked aircraft being delayed, disrupted or grounded.
Around 50 refuellers working for AFS, a joint venture between several fuel firms including Air BP and Total) will join the action next month in a dispute over changes to terms and conditions for new staff recruited since January.
According to Unite, these include reduced pension and sickness benefits.