De Juniac will take up his new role on August 1, replacing Tony Tyler who is retiring.
“I would like to thank all those at Air France-KLM who for almost five years now have been fully committed to achieving together our recovery and restoring the conditions for growth. Working for Air France-KLM is a source of great pride," he said.
"I will continue to fulfil my responsibilities until I hand over to my successor at the end of July, and I will continue to defend air transport and all airlines – including Air France-KLM – in my new role."